One way would be to hormone the females to see how they color up. No idea if this will be harmful to them or affect their fertility, but there are claims that it will have a negative impact. The other is the split them up as best you can based on dorsal and caudal fin patterns/color.
If you do the latter, you would have to spawn the females with their "mate" and then grow out the fry. You are looking for males to color up and look like their father, and not like a mix of the two. This could take a year or more. Anything female that does not throw males that match the father are likely in the wrong tank. This is by no means fool proof.
Aside from not putting them together to begin with, I would get new females and use these females to spawn Syno. multies.
Selling them off as "assorted peacocks" really isn't very responsible IMHO.