My thoughts are that it won't work as well as you would like. First off, you are assuming that your first singleton goby will be a good breeder, of decent stock and genetics, and will accept a partner from among the juveniles later. Either way, it will out-compete younger/smaller gobies that may be better choices from which a pair should form. You essentially take away the choice from the other gobies. My experience has been that forced pairs do not behave as well as those formed from a group of equals.
My male gobies have outlived their female partners. Right now I've got two old widowers whom I don't trust with younger gobies. I reintroduced a female who had previously bred with the male in my avatar after his partner died, the three were a trio for about six months. But the widowed male bred with the 2nd female and then killed her. I hadn't anticipated losing all my breeding females, and so have been conservative with my growing juveniles, because they just wouldn't stand a chance against the older, larger, smarter males if they decided to be nasty.
My male gobies have outlived their female partners. Right now I've got two old widowers whom I don't trust with younger gobies. I reintroduced a female who had previously bred with the male in my avatar after his partner died, the three were a trio for about six months. But the widowed male bred with the 2nd female and then killed her. I hadn't anticipated losing all my breeding females, and so have been conservative with my growing juveniles, because they just wouldn't stand a chance against the older, larger, smarter males if they decided to be nasty.